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However, as the chain length increases the solubility of the fatty acids in water decreases very rapidly, so that the longer chain fatty acids have very little effect on the pH of a hardcore galleries plump rumps solution. The significance of their pKa values therefore only has relevance to the types of reaction that they take part in. Even those fatty acids that are insoluble in water will dissolve hardcore galleries plump rumps in warm ethanol, and can be titrated with sodium hydroxide solution using phenolphthalein as an indicator hardcore galleries plump rumps to a pale pink endpoint. This analysis is used to determine the free fatty acid content of fats, i.e. the proportion of the triglycerides that have been hydrolyzed. [edit] Autoxidation and rancidity See also: Rancidification Fatty acids at room temperature undergo a chemical change known as autoxidation.
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